Al3Cl6
Aluminium chloride dimer
Al
2
Cl
6
  
 
Real, long lived, electronically neutral reagent chemical.

Gram formula weight (molecular mass) = 266.68
Melting point = 177 °C sublimes
Solubility in organics = slightly soluble


Moisture sensitive: fumes of HCl on exposure to air. AlCl3 is nothing like AlCl3 hexahydrate.At high temperatures in the gas phase, aluminium chloride exists as discrete trigonal planar AlCl3 species, but on cooling these dimerise to Al2Cl6. Aluminium chloride is a halophilic Lewis acid with a strong affinity for chloride ion.
Wikipedia Page:

Aluminium chloride dimer
is defined with respect to the entities below:
The entities below are defined with respect to:
Aluminium chloride dimer
Catalyst (AS/A2 generic)


Hard Lewis acid (generic)


Lewis acid (AS/A2 generic)


Lobe-LUMO Lewis acid (generic)


Molecular material (generic)


Period 3 Chlorides (AS/A2 generic)


Type 15 Lewis acid/base complex (generic)


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