Interactions | Reactions | Processes
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Classified as: Type 14 Lewis Acid/Base Complexation Chemistry
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Type 14 complexes are often generated as reactive intermediates with the Complex anion Lewis base acting as a non-nucleophilic counter ion to reactive electrophilic Lobe-LUMO Lewis acid.
Friedel-Crafts reactions, for example, employ Type 14 Lewis acid/base complexes. For more information look in the Chemogenesis webbook sections on Lewis acids and Lewis bases and the Lewis acid/base interaction matrix.
Cl+ |
+ |
[AlCl4]– |
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Cl+ / [AlCl4]– |
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[NO2]+ |
+ |
[BF4]– |
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[NO2]+[BF4]– |
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Br+ |
+ |
[FeBr4]– |
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Br+ [FeBr4]– |
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R+ |
+ |
[AlCl4]– |
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R+ [AlCl4]– |
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[RCO]+ |
+ |
[AlCl4]– |
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+ |
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[N5]+ |
+ |
[AsF6]– |
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[N5]+ [AsF6]– |
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Cl+ |
+ |
[ClO4]– |
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Cl+ [ClO4]– |
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[XeF]+ |
+ |
[PtF6]– |
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[XeF]+ [PtF6]– |
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© Mark R. Leach 1999 –
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