Interactions | Reactions | Processes



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Classified as: Substitution: Radical Nucleophilic First Order




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A number of R-Nfg species which for steric reasons are inert to normal nucleophilic substitution conditions are susceptible to nucleophilic substitution in the presence of UV light.

RCOCl
  +  
R2CuLi
  +  
        

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  +  
I2
  +  
CuCl2
        

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  +  
CuCl
        
  +  
N2
  +  
Cu+

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  +  
CuBr
        
  +  
N2
  +  
Cu+

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  +  
NaI
        
  +  
N2
  +  
Na+

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  +  
CuCN
        
  +  
N2
  +  
Cu+

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  +  
H3PO2
  +  
[H]
        
  +  
N2

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  +  
R2CuLi
        

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R2CuLi
  +  
RBr
        
R–R

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  +  
  +  
hν
        
  +  
Br–

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  +  
  +  
hν
        
  +  
Br–

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  +  
  +  
hν
        
  +  
Br–

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© Mark R. Leach 1999 –


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