Interactions | Reactions | Processes



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Classified as: Substitution: Concerted




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Second order nucleophilic and radical substitution reactions are concerted.

For more information look in the Chemogenesis webbook section substitution, transfer, abstraction, displacement (STAD).

RCOOH
  +  
CH2N2
        
  +  
N2

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  +  
[N3]–
        
  +  
Cl–

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  +  
CH3COOH
        
  +  
  +  
HCl

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CH3I
  +  
[OH]–
        
CH3OH
  +  
I–

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CH3I
  +  
(CH3)3N
        
[(CH3)4N]+
  +  
I–

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[(CH3)4N]+
  +  
[OH]–
        
CH3OH
  +  
(CH3)3N

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[(CH3)4N]+
  +  
H2S
        
[CH3–SH2]+
  +  
(CH3)3N

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(CH3)2CHBr
  +  
CH3CH2O–
  +  
CH3CH2OH
        
CH3–CH=CH2
  +  
  +  
Br–
  +  
CH3CH2OH

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  +  
[OH]–
        
  +  
(CH3)3N

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CH2ClCH2Cl
  +  
2
        
PhS(CH2)2SPh
  +  
2
Cl–

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(CH3)2CHBr
  +  
        
  +  
Br–

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  +  
CH3I
        
  +  
I–

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  +  
Br2
        

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  +  
[Et3O]+[BF4]–
  +  
        
  +  
  +  
Li+
  +  
[BF4]–
  +  

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  +  
CH3CH2I
        
  +  
  +  
Li+
  +  
I–

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CH3I
  +  
[SCN]–
        
N≡C–S–CH3

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RCOCl
  +  
[SCN]–
        

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CH3I
  +  
[NO2]–
        
CH3–NO2

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CH3I
  +  
        

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  +  
        

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R–I
  +  
NaCN
        
R–CN
  +  
NaI

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R2NH
  +  
HNO2
        
R2N–NO

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[R–S]–
  +  
N≡C–Cl
        
R–S–C≡N
  +  
Cl–

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RMgX
  +  
N≡C–Cl
        
R–CN
  +  
Cl–

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RMgX
  +  
I–C≡N
        
R–I
  +  
[CN]–

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ZrC
  +  
3
Pt
        
ZrPt3
  +  
C

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  +  
AlCl3
        
  +  
[AlCl4]–

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  +  
AlCl3
        
  +  
[AlCl4]–

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© Mark R. Leach 1999 –


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