Interactions | Reactions | Processes
Warning: Undefined variable $contentTYPE in /home/www/chemthes/rxn.php on line 104
Classified as: Addition: 1,1
Warning: Undefined variable $contentTEXT in /home/www/chemthes/rxn.php on line 234
1,1-Addition involves two species (W and X), usually an electrophile and a nucleophile, attaching to the same atomic centre, usually carbon. Carbenes are divalent carbon centres which partake in 1,1-additions.
For more information look in the Chemogenesis webbook section on addition reactions.
CO |
+ |
Cl2 |
 |
|
|
 |
|
|
|
|
|
CO |
+ |
HCl |
|
|
|
 |
|
|
|
|
|
 |
+ |
CO |
+ |
HCl |
+ |
AlCl3 |
|
 |
+ |
[AlCl4]– |
+ |
H+ |
|
|
|
CO |
+ |
H2 |
|
|
|
HCHO |
|
|
|
|
|
CO |
+ |
2 |
H2 |
|
|
|
CH3OH |
|
|
|
|
|
CO |
+ |
H2O |
|
|
|
HCOOH |
|
|
|
|
|
CO |
+ |
H2O |
+ |
NaOH |
|
|
HCOONa |
+ |
H2O |
|
|
|
|
CO |
+ |
(CH3)2NH |
+ |
NaOCH3 |
+ |
CH3OH |
|
 |
|
|
|
|
|
CH3–CH=CH2 |
+ |
CO |
+ |
H2 |
|
|
 |
|
|
|
|
|
HC≡CH |
+ |
CO |
+ |
Ni(CO)4 |
+ |
H2O |
|
 |
|
|
|
|
|
H2C=CH2 |
+ |
CO |
+ |
H2O |
+ |
Ni(CO)4 |
|
CH3CH2COOH |
|
|
|
|
|
 |
+ |
CO |
+ |
H2O |
+ |
H+ |
+ |
H+(aq) |
(CH3)3C–COOH |
|
|
|
|
|
CH3OH |
+ |
CO |
|
|
|
CH3COOH |
|
|
|
|
|
 |
+ |
CO |
|
|
|
(CH3CO)2CO |
|
|
|
|
|
 |
+ |
CHCl3 |
+ |
 |
|
|
 |
+ |
(CH3)3COH |
+ |
KCl |
|
|
|
H2C=CH2 |
+ |
CO |
+ |
H2 |
|
|
 |
|
|
|
|
|
CH3OH |
+ |
CO |
+ |
NaOCH3 |
|
|
|
|
|
|
|
|
CH3–CH=CH2 |
+ |
CO |
+ |
H2 |
|
|
|
+ |
 |
|
|
|
|
Si |
+ |
3 |
HCl |
|
|
|
SiHCl3 |
+ |
H2 |
|
|
|
|
Si |
+ |
4 |
HCl |
|
|
|
SiCl4 |
+ |
2 |
H2 |
|
|
|
|
CO/H2 Syngas |
|
|
|
|
CH3OH |
|
|
|
|
|
CO + 2H2 |
|
|
|
|
CH3OH |
|
|
|
|
|
CO |
+ |
CH3NH2 |
+ |
NaOCH3 |
+ |
CH3OH |
|
 |
|
|
|
|
|
CO |
+ |
NH3 |
+ |
NaOCH3 |
+ |
CH3OH |
|
HCONH2 |
|
|
|
|
|
HC≡CH |
+ |
CO |
+ |
Ni(CO)4 |
+ |
CH3OH |
|
 |
|
|
|
|
|
© Mark R. Leach 1999 –
Queries, Suggestions, Bugs, Errors, Typos...
If you have any:
Queries
Comments
Suggestions
Suggestions for links
Bug, typo or grammatical error reports about this page,please contact Mark R. Leach, the author, using mark@meta-synthesis.com